Tris(N-Hydroxyethyl) Hexahydrotriazine
- Preservatives
- CAS 4719-04-4
- IUPAC: 1,3,5-tris(2-hydroxyethyl)hexahydro-s-triazine
Tris(N-Hydroxyethyl) Hexahydrotriazine (CAS 4719-04-4) appears in 2 of the 1,812 car-care products CarCareTruth tracks (as of June 2026). It is readily biodegradable.
Functions as a formaldehyde-releasing preservative — hydrolyzes in water to release trace formaldehyde. At typical use concentrations in consumer products (0.05–0.3%), formaldehyde release is at low levels. Formaldehyde is a known sensitizer (asthmagen) and Group 1 carcinogen (IARC), but consumer product concentrations are well below regulatory thresholds. Not Prop 65-listed as the triazine itself; formaldehyde release may be relevant if concentration is above 0.05% free formaldehyde at product level — typically not the case in diluted consumer formulas. European Biocidal Products Regulation (BPR) approved for PT06 (preservatives for products as stored) and PT13 (working or cutting fluid preservatives).
Tris(N-Hydroxyethyl) Hexahydrotriazine (CAS 4719-04-4), also known as Grotan BK or Hexahydrotriazine HHT, is a formaldehyde-releasing biocide used as a preservative in water-based industrial and consumer cleaning products. It releases formaldehyde slowly under use conditions, which provides antimicrobial activity. At typical consumer product concentrations (0.1–0.3%), total formaldehyde release is well below OSHA and EU regulatory thresholds. It is considered significantly less hazardous than isothiazolinone-based preservatives (CMIT/MIT) and does not carry H317 (skin sensitizer) classification at product level when used at normal concentrations. Not a Prop 65-listed substance. Biodegradable. No aquatic toxicity classification at product-level concentrations. Approved under EU BPR for use in industrial and consumer products.
Health & environment profile
- VOC
- no
- Prop 65 listed
- no
- Asthmagen
- no
- EPA Safer Choice
- no
- Aquatic toxicity
- no
- Biodegradable
- yes
- Bioaccumulative
- no
- Persistent
- no
- Ozone depleting
- no
- Microplastic
- no
- PFAS
- no
- Env. score
- 4/5
Common questions about Tris(N-Hydroxyethyl) Hexahydrotriazine
- What is Tris(N-Hydroxyethyl) Hexahydrotriazine used for in car care?
- Biocide and preservative — prevents microbial growth in water-based cleaning formulations
- Is Tris(N-Hydroxyethyl) Hexahydrotriazine a VOC?
- No. Tris(N-Hydroxyethyl) Hexahydrotriazine is not classified as a volatile organic compound (VOC).
- Is Tris(N-Hydroxyethyl) Hexahydrotriazine on California's Proposition 65 list?
- No. Tris(N-Hydroxyethyl) Hexahydrotriazine is not on California's Proposition 65 list.
- Is Tris(N-Hydroxyethyl) Hexahydrotriazine biodegradable?
- Yes. Tris(N-Hydroxyethyl) Hexahydrotriazine has a confirmed biodegradable profile.
2 products contain this

Griot's Garage Plastic All-in-Oneheadlight-restoration
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Health and environment notes translate the manufacturer Safety Data Sheet, the GHS classification, and authoritative regulatory listings (California Prop 65, EPA). Not medical advice. They describe the ingredient itself; whether a hazard applies to a finished product depends on its concentration and how it's used.