CarCareTruth

Sodium Thioglycolate

  • Reducers
  • CAS 367-51-1
  • IUPAC: Sodium 2-mercaptoacetate

Sulfur odor. Skin and eye irritant at concentration (H315, H319). Harmful if swallowed (H302, LD50 oral mouse 504 mg/kg). Sodium salt form appears milder than ammonium thioglycolate at consumer product-level classification.

Sodium thioglycolate is the sodium salt of thioglycolic acid — the same iron-reactive chemistry as ammonium thioglycolate but using sodium as the counterion. It reacts with iron oxide (brake dust) to form a purple iron-thioglycolate complex, providing visible feedback that decontamination is occurring. Used in Griot's Garage Iron & Fallout Remover at 25% concentration. At the product level, Griot's SDS classifies the mixture as WARNING with H302/H315/H319 only — notably milder than products using ammonium thioglycolate at similar concentrations, which typically carry DANGER with H318 (serious eye damage) and H312 (harmful in contact with skin). Whether this reflects the salt form, concentration effects, or formulation choices is not clear from the SDS alone. Aerobically biodegradable in wastewater treatment. The purple iron-thioglycolate runoff from wheel cleaning should go to sanitary sewer, not storm drain, as a general best practice for iron-remover rinse water.

Health & environment profile

VOC
no
Prop 65 listed
no
Asthmagen
no
EPA Safer Choice
no
Aquatic toxicity
no
Biodegradable
yes
Bioaccumulative
no
Persistent
no
Ozone depleting
no
Microplastic
no
PFAS
no
Env. score
4/5
Purpose: Iron decontamination (brake dust indicator)

4 products contain this

Health summaries are editorial — we synthesize from SDSs, peer-reviewed sources, and regulatory listings. Not medical advice.