CarCareTruth

Methyl Acetate

  • Other solvents
  • CAS 79-20-9
  • IUPAC: Methyl acetate

Mild CNS depressant and eye/nose irritant at high concentrations (H319, H336). Flash point is 9°C — highly flammable (H225). ACGIH TLV-TWA 200 ppm, OSHA PEL 200 ppm. Brief exposure in well-ventilated conditions is low risk. The flammability is the primary practical concern.

Methyl acetate is a fast-evaporating ester solvent with a mild fruity odor. In aerosol tire shines and paint-care products, it serves as a co-solvent alongside acetone, contributing to rapid film formation and solvent-carrier evaporation. It's notably VOC-exempt under US EPA and CARB regulations, which is why it can be used at 15–45% concentrations without triggering aerosol VOC compliance failures. The GHS classification reflects H225 (highly flammable liquid), H319 (eye irritation), and H336 (narcotic effects — dizziness at sustained high concentrations). In a brief aerosol application outdoors, actual inhalation doses are far below occupational TLVs. Readily hydrolyzes to methanol + acetic acid, both of which degrade quickly — no environmental persistence. Structurally an ester of methanol and acetic acid (methanol + acetic acid → methyl acetate + water). Hydrolysis reverses this reaction in aqueous environments, so environmental fate is rapid and benign.

Health & environment profile

VOC
no
Prop 65 listed
no
Asthmagen
no
EPA Safer Choice
no
Aquatic toxicity
no
Biodegradable
yes
Bioaccumulative
no
Persistent
no
Ozone depleting
no
Microplastic
no
PFAS
no
Env. score
4/5
Purpose: Fast-evaporating carrier solvent in aerosol formulations; co-solvent alongside acetone for cleaning and degreasing

1 product contain this

Health summaries are editorial — we synthesize from SDSs, peer-reviewed sources, and regulatory listings. Not medical advice.