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2-Ethylhexanol

  • Alcohol solvents
  • CAS 104-76-7
  • IUPAC: 2-ethylhexan-1-ol

2-Ethylhexanol (CAS 104-76-7) appears in 1 of the 1,812 car-care products CarCareTruth tracks (as of June 2026). It is classified as a VOC.

H332 (harmful if inhaled, acute inhalation Cat 4) at substance level. Skin irritant (H315) and eye irritant (H319) at substance level. The inhalation exposure risk is primarily relevant for occupational scenarios with direct vapor exposure; consumer pour-into-tank exposure is brief.

2-Ethylhexanol (2-EH; CAS 104-76-7) is a branched C8 primary alcohol produced commercially as a co-product of oxo synthesis (hydroformylation). It is a colorless, slightly oily liquid with a mild, sweet odor and limited water solubility. At the fuel-additive concentrations where it appears (10–15% in diesel treatments), it functions as both a coupling agent — helping dissolve 2-EHN and other actives in the petroleum distillate carrier — and a mild lubricity contributor via its hydroxyl group's boundary-lubrication properties.

In the CarCareTruth context, 2-ethylhexanol appears in diesel fuel additive formulations containing 2-ethylhexyl nitrate (2-EHN). The alcohol is a thermal decomposition product of 2-EHN, and some formulations include it deliberately as a co-solvent. At the mixture concentrations found in consumer diesel treatments, 2-ethylhexanol's primary hazard pathway is brief inhalation during the tank-pour scenario; the compound is more volatile than the heavy-aromatic naphtha carrier and contributes to the inhalation exposure window alongside 2-EHN vapors.

The compound is biodegradable and is not classified as a persistent, bioaccumulative, or toxic (PBT) substance under EU REACH. Its aquatic toxicity at finished-product concentrations is low.

Health & environment profile

VOC
yes
Prop 65 listed
no
Asthmagen
no
EPA Safer Choice
no
Aquatic toxicity
no
Biodegradable
yes
Bioaccumulative
no
Persistent
no
Ozone depleting
no
Microplastic
no
PFAS
no
Env. score
3/5
Purpose: Branched-chain fatty alcohol used as a coupling agent, carrier solvent, and lubricity additive in diesel fuel treatments and industrial lubricant formulations.

Common questions about 2-Ethylhexanol

What is 2-Ethylhexanol used for in car care?
Branched-chain fatty alcohol used as a coupling agent, carrier solvent, and lubricity additive in diesel fuel treatments and industrial lubricant formulations.
Is 2-Ethylhexanol a VOC?
Yes. 2-Ethylhexanol is classified as a volatile organic compound (VOC).
Is 2-Ethylhexanol on California's Proposition 65 list?
No. 2-Ethylhexanol is not on California's Proposition 65 list.
Is 2-Ethylhexanol biodegradable?
Yes. 2-Ethylhexanol has a confirmed biodegradable profile.

1 product contain this

Related

Health and environment notes translate the manufacturer Safety Data Sheet, the GHS classification, and authoritative regulatory listings (California Prop 65, EPA). Not medical advice. They describe the ingredient itself; whether a hazard applies to a finished product depends on its concentration and how it's used.